The Hoopes process is a Metallurgy process, used to obtain aluminium metal of very high purity (about 99.99% pure). The process was patented by William Hoopes, a chemist of the Aluminum Company of America (ALCOA), in 1925.
Introduction
It is a method used to obtain aluminium of very high purity. The metal obtained in the Hall–Héroult process is about 99.5% pure, and for most purposes it is taken as pure metal.
However, further purification of aluminium can be carried out by the Hoopes process. This is an electrolytic process.
The process
The cell used in this process consists of an iron tank lined with carbon at the bottom.
A molten alloy of
copper, crude aluminium and
silicon is used as the anode. It forms the lowermost layer in the cell.
The middle layer consists of molten mixture of
fluorides of
sodium, aluminium and
barium (
cryolite + BaF
2).
The uppermost layer consists of molten aluminium.
A set of
graphite rods dipped in molten aluminium serve as the cathode.
During
electrolysis, Al
3+ ions from the middle layer migrate to the upper layer, where they are reduced to aluminum by gaining 3
Electron.
Equal numbers of Al
3+ ions are produced in the lower layer. These ions migrate to the middle layer. Pure aluminium is tapped off from time to time. The Hoopes process gives about 99.99% pure aluminium.
Further reading
